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arxiv: cond-mat/0009018 · v3 · submitted 2000-09-01 · ❄️ cond-mat.str-el · cond-mat.soft

Mediation of Long Range Charge Transfer by Kondo Bound States

classification ❄️ cond-mat.str-el cond-mat.soft
keywords chargelongtransferboundcouplingintermediatekondomodel
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We present a theory of non-equilibrium long range charge transfer between donor and acceptor centers in a model polymer mediated by magnetic exciton (Kondo) bound states. Our model produces electron tunneling lengths easily exceeding 10$\AA$, as observed recently in DNA and organic charge transfer systems. This long ranged tunneling is effective for weak to intermediate donor-bridge coupling, and is enhanced both by weak to intermediate strength Coulomb hole-electron attraction (through the orthogonality catastrophe) and by coupling to local vibrational modes.

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