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arxiv: cond-mat/0106291 · v1 · submitted 2001-06-15 · ❄️ cond-mat.soft

Orientations of the lamellar phase of block copolymer melts under oscillatory shear flow

classification ❄️ cond-mat.soft
keywords flowblockcopolymerlamellarmeltphasesheartransition
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We develop a theory to describe the reorientation phenomena in the lamellar phase of block copolymer melt under reciprocating shear flow. We show that similar to the steady-shear, the oscillating flow anisotropically suppresses fluctuations and gives rise to the parallel-perpendicular orientation transition. The experimentally observed high-frequency reverse transition is explained in terms of interaction between the melt and the shear-cell walls.

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