Orientations of the lamellar phase of block copolymer melts under oscillatory shear flow
classification
❄️ cond-mat.soft
keywords
flowblockcopolymerlamellarmeltphasesheartransition
read the original abstract
We develop a theory to describe the reorientation phenomena in the lamellar phase of block copolymer melt under reciprocating shear flow. We show that similar to the steady-shear, the oscillating flow anisotropically suppresses fluctuations and gives rise to the parallel-perpendicular orientation transition. The experimentally observed high-frequency reverse transition is explained in terms of interaction between the melt and the shear-cell walls.
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