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arxiv: cond-mat/0109496 · v1 · submitted 2001-09-26 · ❄️ cond-mat

Mixed-Valence Tetranuclear Manganese Single-Molecule Magnets

classification ❄️ cond-mat
keywords anionmagnetsmanganesemixed-valencesingle-moleculetetranuclearcharacterizationscomplexes
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The preparations, X-ray structures, and detailed physical characterizations are presented for two new mixed-valence tetranuclear manganese complexes that function as single-molecule magnets (SMM's): [Mn4(hmp)6Br2(H2O)2]Br2.4H2O and [Mn4(6-me-hmp)6Cl4].4H2O, where hmp- is the anion of 2-hydroxymethylpyridine and 6-me-hmp- is the anion of 6-methyl-2-hydroxymethylpyridine.

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