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arxiv: cond-mat/0206108 · v1 · submitted 2002-06-07 · ❄️ cond-mat.dis-nn · cond-mat.stat-mech

Percolation, depinning, and avalanches in capillary condensation of gases in disordered porous solids

classification ❄️ cond-mat.dis-nn cond-mat.stat-mech
keywords capillarycondensationdepinningdisorderedgaseshysteresisapplyingassociated
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We propose a comprehensive theoretical description of hysteresis in capillary condensation of gases in mesoporous disordered materials. Applying mean-field density functional theory to a coarse-grained lattice-gas model, we show that the morphology of the hysteresis loops is influenced by out-of-equilibrium transitions that are different on filling and on draining. In particular, desorption may be associated to a depinning process and be percolation-like without explicit pore-blocking effects.

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