Symmetry breaking and restoring under high pressure: the amazing behaviour of the "simple" alkali metals
classification
❄️ cond-mat.mtrl-sci
keywords
phasepressureunderalkalihighmetalsoscillationsrestoring
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We argue that an ionic lattice surrounded by a Fermi liquid changes phase several times under pressure, oscillating between the symmetric phase and a low-symmetry dimerized structure, as a consequence of Friedel oscillations in the pair potential. Phase oscillations explain the tendency towards dimerization which has been recently reported for the light alkali metals under high pressure. Moreover, a restoring of the symmetric phase is predicted for such elements at an even higher density.
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