Spin-Wave Description of Nuclear Spin-Lattice Relaxation in Mn₁₂O₁₂ Acetate
classification
❄️ cond-mat.stat-mech
cond-mat.str-el
keywords
acetateclusternuclearrelaxationspinspin-latticespin-waveapplied-field
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In response to recent nuclear-magnetic-resonance (NMR) measurements on the molecular cluster Mn_{12}O_{12} acetate, we study the nuclear spin-lattice relaxation rate 1/T_1 developing a modified spin-wave theory. Our microscopic new approach, which is distinct from previous macroscopic treatments of the cluster as a rigid spin of S=10, not only excellently interprets the observed temperature and applied-field dependences of 1/T_1 for ^{55}Mn nuclei but also strongly supports the ^{13}C NMR evidence for spin delocalization over the entire molecule.
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