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arxiv: cond-mat/0304087 · v1 · submitted 2003-04-03 · ❄️ cond-mat.soft

Onsager model for a variable dielectric permittivity near an interface

classification ❄️ cond-mat.soft
keywords dielectricinterfacepermittivityonsagerableapproachasymptoticbispherical
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Using a generalisation of an Onsager type approach, we are able to predict a dielectric permittivity profile of an inhomogeneous dipolar fluid in the presence of a dielectric interface. The reaction and cavity fields are calculated semi-analytically using bispherical coordinates. An asymptotic expression for the local permittivity is derived as a function of distance from the interface.

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