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arxiv: cond-mat/0306089 · v2 · submitted 2003-06-04 · ❄️ cond-mat.dis-nn · cond-mat.soft

The Kovacs effect in model glasses

classification ❄️ cond-mat.dis-nn cond-mat.soft
keywords effectkovacsanalysisdiscussdomainglassyhumpquantitative
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We discuss the `memory effect' discovered in the 60's by Kovacs in temperature shift experiments on glassy polymers, where the volume (or energy) displays a non monotonous time behaviour. This effect is generic and is observed on a variety of different glassy systems (including granular materials). The aim of this paper is to discuss whether some microscopic information can be extracted from a quantitative analysis of the `Kovacs hump'. We study analytically two families of theoretical models: domain growth and traps, for which detailed predictions of the shape of the hump can be obtained. Qualitatively, the Kovacs effect reflects the heterogeneity of the system: its description requires to deal not only with averages but with a full probability distribution (of domain sizes or of relaxation times). We end by some suggestions for a quantitative analysis of experimental results.

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