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arxiv: cond-mat/0308190 · v1 · submitted 2003-08-10 · ❄️ cond-mat.mtrl-sci

Remarkable thermal stability of BF3-doped polyaniline

classification ❄️ cond-mat.mtrl-sci
keywords bf3-dopedpaniconductivitypolyanilineremarkablespectroscopystabilitythermal
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We show that the recently synthesized BF3-doped polyaniline (PANI) exhibits remarkable stability against thermal ageing. Unlike the protonated PANI, which shows rapid degradation of the conductivity on heating in air, BF3-doped PANI shows more than an order of magnitude improvement in conductivity. We employ x-ray photoelectron spectroscopy (XPS), fourier transform infra-red (FTIR) spectroscopy, and x-ray diffraction (XRD) to understand this unexpected phenomenon.

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