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arxiv: cond-mat/0405253 · v3 · submitted 2004-05-12 · ❄️ cond-mat.stat-mech

What is the length of a knot in a polymer?

classification ❄️ cond-mat.stat-mech
keywords lengthknotringregimebelowcarlocollapsedcompetition
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We give statistical definitions of the length, l, of a loose prime knot tied into a long, fluctuating ring macromolecule. Monte Carlo results for the equilibrium, good solvent regime show that < l > ~ N^t, where N is the ring length and t ~ 0.75 is independent of the knot topology. In the collapsed regime below the theta temperature, length determinations based on the entropic competition of different knots within the same ring show delocalization (t~1).

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