Low-temperature structural transition in FeCr₂S₄

Transmission electron microscopy studies of [110] and [111] oriented FeCr_2S_4 single crystals at different temperatures reveal a structural transition at low temperatures indicating a cubic-to-triclinic symmetry reduction within crystallographic domains. The overall crystal symmetry was found to be reduced from Fd3m to F-43m. The triclinic distortions were suggested to result from the combined actions of tetragonal distortions due to the Jahn-Teller active Fe^2+ ions and trigonal distortions due to a displacement of the Cr^3+ ions in the <111> direction.