Structural Behavior of Non-Oxide Perovskite Superconductor MgCNi₃ at Pressures up to 32 GPa
classification
❄️ cond-mat.supr-con
keywords
earliermgcninon-oxideperovskitepressurerangestructuralsuperconductor
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We report the pressure dependence of the structural parameters of the non-oxide perovskite superconductor MgCNi$_{3}$ up to 32 GPa using a diamond anvil cell and synchrotron x-rays at room temperature. The structure of the compound remains in the Pm-3m cubic symmetry throughout the pressure range. The bulk modulus $B_{0}=156.9\pm0.2$GPa with $B_{0}^{\prime}=9.8$obtained by fitting the pressure-volume data is in good agreement with theoretical calculations reported earlier. An anomalous shift of the (111) and (200) lines observed above 9 GPa indicates a possible local short range distortion that is consistent with earlier studies.
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