Are defect models consistent with the entropy and specific heat of glass-formers?
classification
❄️ cond-mat.stat-mech
cond-mat.dis-nn
keywords
defectglass-formersheatmodelsspecificacadapproachescannot
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We show that point-like defect model of glasses cannot explain thermodynamic properties of glass-formers, as for example the excess specific heat close to the glass transition, contrary to the claim of J.P. Garrahan, D. Chandler [Proc. Natl. Acad. Sci. 100, 9710 (2003)]. More general models and approaches in terms of extended defects are also discussed.
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