pith. sign in

arxiv: cond-mat/0503029 · v1 · submitted 2005-03-02 · ❄️ cond-mat.stat-mech

Comment on "First-order phase transitions: equivalence between bimodalities and the Yang-Lee theorem"

classification ❄️ cond-mat.stat-mech
keywords distributionsassociatedcanonicalchomazentropyequivalencefirst-orderfunctions
0
0 comments X
read the original abstract

I discuss the validity of a result put forward recently by Chomaz and Gulminelli [Physica A 330 (2003) 451] concerning the equivalence of two definitions of first-order phase transitions. I show that distributions of zeros of the partition function fulfilling the conditions of the Yang-Lee Theorem are not necessarily associated with nonconcave microcanonical entropy functions or, equivalently, with canonical distributions of the mean energy having a bimodal shape, as claimed by Chomaz and Gulminelli. In fact, such distributions of zeros can also be associated with concave entropy functions and unimodal canonical distributions having affine parts. A simple example is worked out in detail to illustrate this subtlety.

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.