pith. sign in

arxiv: cond-mat/0506123 · v1 · submitted 2005-06-06 · ❄️ cond-mat.soft

Nonequilibrium molecular dynamics of complex fluids near the gel point

classification ❄️ cond-mat.soft
keywords approxepsilonlambdadimensionsdivergedynamicsmolecularnonequilibrium
0
0 comments X
read the original abstract

We have carried out nonequilibrium molecular dynamics simulations of a system of crosslinked particles under shear flow conditions. As the fraction of crosslinks $p$ is increased the system approaches a gel point at which the shear viscosity $\eta$ and the first and second normal stress coefficients $\Psi_1$ and $\Psi_2$ diverge. All three quantities seem to diverge with a power law form: $\eta\sim \epsilon^{-s}$, $\Psi_{1,2}\sim\epsilon^{-\lambda}$ where $\epsilon =p_c-p$ and $s\approx 0.7$ and $\lambda\approx 3.15$ in three dimensions and $s\approx 2.0$ and $\lambda\approx 6.0$ in two dimensions.

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.