Suppressed magnetization in La_(0.7)Ca_(0.3)MnO₃/YBa₂Cu₃O_(7-δ) superlattices

We studied the magnetic properties of La$_{0.7}$Ca$_{0.3}$MnO$_3$ / YBa$_2$Cu$_3$O$_{7-\delta}$ superlattices. Magnetometry showed that with increasing YBa$_2$Cu$_3$O$_{7-\delta}$ layer thickness the saturation magnetization per La$_{0.7}$Ca$_{0.3}$MnO$_3$ layer decreases. From polarized neutron reflectometry we determined that this magnetization reduction is due to an inhomogenous magnetization depth profile arising from the suppression of magnetization near the La$_{0.7}$Ca$_{0.3}$MnO$_3$ / YBa$_2$Cu$_3$O$_{7-\delta}$ interface. Electron energy loss spectroscopy indicates an increased 3d band occupation of the Mn atoms in the La$_{0.7}$Ca$_{0.3}$MnO$_3$ layers at the interface. Thus, the suppression of ferromagnetic order at the La$_{0.7}$Ca$_{0.3}$MnO$_3$ / YBa$_2$Cu$_3$O$_{7-\delta}$ interface is most likely due to charge transfer between the two materials.