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arxiv: cond-mat/0601435 · v1 · submitted 2006-01-19 · ❄️ cond-mat.stat-mech

Fluctuation theorem for constrained equilibrium systems

classification ❄️ cond-mat.stat-mech
keywords fluctuationsystemsequilibriumphase-spacestatestheoremconstrainedcontraction
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We discuss the fluctuation properties of equilibrium chaotic systems with constraints such as iso-kinetic and Nos\'e-Hoover thermostats. Although the dynamics of these systems does not typically preserve phase-space volumes, the average phase-space contraction rate vanishes, so that the stationary states are smooth. Nevertheless finite-time averages of the phase-space contraction rate have non-trivial fluctuations which we show satisfy a simple version of the Gallavotti-Cohen fluctuation theorem, complementary to the usual fluctuation theorem for non-equilibrium stationary states, and appropriate to constrained equilibrium states. Moreover we show these fluctuations are distributed according to a Gaussian curve for long-enough times. Three different systems are considered here, namely (i) a fluid composed of particles interacting with Lennard-Jones potentials; (ii) a harmonic oscillator with Nos\'e-Hoover thermostatting; (iii) a simple hyperbolic two-dimensional map.

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