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arxiv: cond-mat/0601509 · v1 · submitted 2006-01-23 · ❄️ cond-mat.str-el · cond-mat.mtrl-sci

How strongly correlated is MnSi?

classification ❄️ cond-mat.str-el cond-mat.mtrl-sci
keywords mnsivalencex-rayexperimentalgroundmixedstateabsorption
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We present an experimental study of the electronic structure of MnSi. Using X-ray Absorption Spectroscopy, X-ray photoemission and X-ray fluorescence we provide experimental evidence that MnSi has a mixed valence ground state. We show that self consistent LDA supercell calculations cannot replicate the XAS spectra of MnSi, while a good match is achieved within the atomic multiplet theory assuming a mixed valence ground state. We discuss the role of the electron-electron interactions in this compound and estimate that the valence fluctuations are suppressed by a factor of 2.5, which means that the Coulomb repulsion is not negligible.

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