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arxiv: cond-mat/0701011 · v1 · submitted 2006-12-30 · ❄️ cond-mat.mtrl-sci · cond-mat.other

A crystallographic phase transition within the magnetically ordered state of Ce₂Fe₁7

classification ❄️ cond-mat.mtrl-sci cond-mat.other
keywords superstructureadditionaldiffractionexperimentsobservedorderedreflectionsstate
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X-ray diffraction experiments were performed on polycrystalline and single-crystal specimens of Ce$_{2}$Fe$_{17}$ at temperatures between 10 K and 300 K. Below $T_{\mathrm{t}}$ = 118$\pm$2 K, additional weak superstructure reflections were observed in the antiferromagnetically ordered state. The superstructure can be described by a doubling of the chemical unit cell along the $\mathbf{c}$ direction in hexagonal notation with the same space group $R \bar{3} m$ as the room-temperature structure. The additional antiferromagnetic satellite reflections observed in earlier neutron diffraction experiments can be conclusively related to the appearance of this superstructure.

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