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arxiv: cond-mat/9207015 · v1 · pith:IMZKJUDInew · submitted 1992-07-15 · ❄️ cond-mat

Fast-diffusion mean-field theory for k-body reactions in one dimension

classification ❄️ cond-mat
keywords mean-fieldreactionstheoryannihilationchemicalhard-corek-bodyaccounts
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We derive an improved mean-field approximation for k-body annihilation reactions kA --> inert, for hard-core diffusing particles on a line, annihilating in groups of k neighbors with probability 0 < q <= 1. The hopping and annihilation processes are correlated to mimic chemical reactions. Our new mean-field theory accounts for hard-core particle properties and has a larger region of applicability than the standard chemical rate equation especially for large k values. Criteria for validity of the mean-field theory and its use in phenomenological data fits are derived. Numerical tests are reported for k=3,4,5,6.

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