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arxiv: cond-mat/9306031 · v1 · submitted 1993-06-10 · ❄️ cond-mat

Nonlinear Hydrodynamics of a Hard Sphere Fluid Near the Glass Transition

classification ❄️ cond-mat
keywords behaviordensityfluidhardresultsspheresystemaccording
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We conduct a numerical study of the dynamic behavior of a dense hard sphere fluid by deriving and integrating a set of Langevin equations. The statics of the system is described by a free energy functional of the Ramakrishnan-Yussouff form. We find that the system exhibits glassy behavior as evidenced through stretched exponential decay and two-stage relaxation of the density correlation function. The characteristic times grow with increasing density according to the Vogel-Fulcher law. The wavenumber dependence of the kinetics is extensively explored. The connection of our results with experiment, mode coupling theory, and molecular dynamics results is discussed.

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