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arxiv: cond-mat/9609123 · v1 · submitted 1996-09-13 · ❄️ cond-mat

Infrared response of ordered polarons in layered perovskites

classification ❄️ cond-mat
keywords infraredabsorptionbeenchargechargedconductivitydetecteddifferences
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We report on the infrared absorption spectra of three oxides where charged superlattices have been recently observed in diffraction experiments. In La$_{1.67}$Sr$_{0.33}$NiO$_4$, polaron localization is found to suppress the low-energy conductivity through the opening of a gap and to split the $E_{2u}$-$A_{2u}$ vibrational manifold of the oxygen octahedra. Similar effects are detected in Sr$_{1.5}$La$_{0.5}$MnO$_4$ and in La$_2$NiO$_{4+y}$, with peculiar differences related to the type of charge ordering.

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