Off center D^- centers in a quantum well in the presence of a perpendicular magnetic field: angular momentum transition and magnetic evaporation

We investigate the effect of the position of the donor in the quantum well on the energy spectrum and the oscillator strength of the D- system in the presence of a perpendicular magnetic field. As a function of the magnetic field we find that when the D- centers are placed sufficiently off-center they undergo singlet-triplet transitions which are similar to those found in many-electron parabolic quantum dots. The main difference is that the number of such transitions depends on the position of the donor and only a finite number of such singlet-triplet transitions are found as function of the strength of the magnetic field. For sufficiently large magnetic fields the two electron system becomes unbound. For the near center D- system no singlet-triplet and no unbinding of the D- is found with increasing magnetic field. A magnetic field vs. donor position phase diagram is presented that depends on the width of the quantum well.