arxiv: cond-mat/9903354 · v1 · submitted 1999-03-23 · ❄️ cond-mat.mtrl-sci

X-ray photoelectron 3s spectra of transition metal oxides

V. R. Galakhov (1) , S. Uhlenbrock (2) , S. Bartkowski (2) , A. V. Postnikov (2) , M. Neumann (2) , L. D. Finkelstein (1) , E. Z. Kurmaev (1) , A. A. Samokhvalov (1)

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L. I. Leonyuk (3) ((1) Institute of Metal Physics Ekaterinburg Russia (2) Osnabrueck University Germany (3) Moscow State University Russia)

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classification ❄️ cond-mat.mtrl-sci

keywords metalspectraoxideschangephotoelectrontransitionx-rayanalysed

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We present metal 3s x-ray photoelectron spectra of different transition metal oxides. The values of the 3s exchange splitting for the 3d metal oxides are given as a function of the 3d electron number in the ground state. The spectra were analysed using the simple two-configuration model of the interatomic configuration mixing. The change of the 3s spectra is ascribed to the change of the charge-transfer energy.

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X-ray photoelectron 3s spectra of transition metal oxides

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