Phase transition from a d_(x²-y²) to d_(x²-y²)+id_(xy) superconductor

The temperature dependencies of specific heat and spin susceptibility of a coupled $d_{x^2-y^2} +id_{xy}$ superconductor in the presence of a weak $d_{xy}$ component are investigated in the tight-binding model (1) on square lattice and (2) on a lattice with orthorhombic distortion. As the temperature is lowered past the critical temperature $T_c$, first a less ordered $d_{x^2-y^2}$ superconductor is created, which changes to a more ordered $d_{x^2-y^2} +id_{xy}$ superconductor at $T_{c1} (<T_c)$. This manifests in two second order phase transitions identified by two jumps in specific heat at $T_c$ and $T_{c1}$. The temperature dependencies of the superconducting observables exhibit a change from power-law to exponential behavior as temperature is lowered below $T_{c1}$ and confirm the new phase transition.