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arxiv: cond-mat/9910451 · v1 · submitted 1999-10-27 · ❄️ cond-mat.stat-mech

Triangle Distribution and Equation of State for Classical Rigid Disks

classification ❄️ cond-mat.stat-mech
keywords basicclosuredensitydistributionequationidentitiesrigidstate
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The triangle distribution function f^(3) for three mutual nearest neighbors in the plane describes basic aspects of short-range order and statistical thermodynamics in two-dimensional many-particle systems. This paper examines prospects for constructing a self-consistent calculation for the rigid-disk system f^(3). We present several identities obeyed by f^(3). A rudimentary closure suggested by scaled-particle theory is introduced. In conjunction with three of the basic identities, this closure leads to a unique f^(3) over the entire density range. The pressure equation of state exhibits qualitatively correct behavior in both the low density and the close-packed limits, but no intervening phase transition appears. We discuss extensions to improved disk closures, and to the three-dimensional rigid sphere system.

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