Neutron structure function moments at leading twist

The experimental data on F2 structure functions of the proton and deuteron were used to construct their moments. In particular, recent measurements performed with CLAS detector at Jefferson Lab allowed to extend our knowledge of structure functions in the large-x region. The phenomenological analysis of these experimental moments in terms of the Operator Product Expansion permitted to separate the leading and higher twist contributions. Applying nuclear corrections to extracted deuteron moments we obtained the contribution of the neutron. Combining leading twist moments of the neutron and proton we found d/u ratio at x->1 approaching 0, although 1/5 value could not be excluded. The twist expansion analysis suggests that the contamination of higher twists influences the extraction of the d/u ratio at x->1 even at Q2-scale as large as 12 (GeV/c)^2.