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arxiv: physics/0610122 · v3 · submitted 2006-10-17 · ⚛️ physics.atom-ph · physics.chem-ph

Helium energy levels including m α⁶ corrections

classification ⚛️ physics.atom-ph physics.chem-ph
keywords energyalphaheliumlevelsstateagreementarbitrarycalculations
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The $m \alpha^6$ correction to energy is expressed in terms of an effective Hamiltonian $H^{(6)}$ for an arbitrary state of helium. Numerical calculations are performed for $n=2$ levels, and the previous result for the $2^3P$ centroid is corrected. While the resulting theoretical predictions for the ionization energy are in moderate agreement with experimental values for $2^3S_1$, $2^3P$, and $2^1S_0$ states, they are in significant disagreement for the singlet state $2^1P_1$.

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