Chaos assisted adiabatic passage

We study the exact dynamics underlying stimulated Raman adiabatic passage (STIRAP) for a particle in a multi-level anharmonic system (the infinite square-well) driven by two sequential laser pulses, each with constant carrier frequency. In phase space regions where the laser pulses create chaos, the particle can be transferred coherently into energy states different from those predicted by traditional STIRAP. It appears that a transition to chaos can provide a new tool to control the outcome of STIRAP.