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arxiv: 0809.3736 · v1 · submitted 2008-09-22 · ⚛️ physics.chem-ph · physics.atom-ph

Electric dipole rovibrational transitions in HD molecule

classification ⚛️ physics.chem-ph physics.atom-ph
keywords dipoleelectricmoleculeratesrovibrationaltransitiontransitionsaccurate
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The rovibrational electric dipole transitions in the ground electronic state of the HD molecule are studied. A simple, yet rigorous formula is derived for the transition rates in terms of the electric dipole moment function $D(R)$, which is calculated in a wide range of $R$. Our numerical results for transition rates are in moderate agreement with experiments and previous calculations, but are at least an order of magnitude more accurate.

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