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Effects of substrate relaxation on adsorption in pores

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arxiv 0810.0262 v1 pith:AWGEB3UX submitted 2008-10-01 cond-mat.mtrl-sci

classification cond-mat.mtrl-sci
keywords relaxationporeseffectsfluidsfoundhostrigidslit
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Fluids in porous media are commonly studied with analytical or simulation methods, usually assuming that the host medium is rigid. By evaluating the substrate's response (relaxation) to the presence of the fluid we assess the error inherent in that assumption. One application is a determination of the ground state of 3He in slit and cylindrical pores. With the relaxation, there results a much stronger cohesion than would be found for a rigid host. Similar increased binding effects of relaxation are found for classical fluids confined within slit pores or nanotube bundles.

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