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arxiv: 0811.2817 · v1 · submitted 2008-11-17 · ❄️ cond-mat.soft

Anomalous diffusion in supercooled liquids: a long-range localisation in particle trajectories

classification ❄️ cond-mat.soft
keywords liquidslocalisationtrajectoriesdiffusionfragilelong-rangeparticlesupercooled
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A statistical analysis of the geometries of particle trajectories in the supercooled liquid state is reported. We examine two structurally different fragile glass-forming liquids simulated by molecular dynamics. In both liquids, the trajectories are found to exhibit a long-range localisation distinct from the short-range localisation within the cage of nearest neighbours. This novel diffusion anomaly is interpreted as a result of the potential-energy landscape topography of fragile glass-formers where the local energy minima coalesce into metabasins - compact domains with low escape probability.

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