Relation between static short-range order and dynamic heterogeneities in a nanoconfined liquid crystal
classification
⚛️ physics.chem-ph
physics.optics
keywords
dynamicstaticcrystaldynamicsheterogeneitiesliquidmolecularnanoconfined
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We analyze the molecular dynamics heterogeneity of the liquid crystal 4-n-octyl-4'-cyanobiphenyl nanoconfined in porous silicon. We show that the temperature dependence of the dynamic correlation length ?wall, which measures the distance over which a memory of the interfacial slowing down of the molecular dynamics persists, is closely related to the growth of the short-range static order arising from quenched random fields. More generally, this result may also shed some light on the connection between static and dynamic heterogeneities in a wide class of condensed and soft matter systems.
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