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Experimental evidence of a body centered cubic iron at the Earth's core condition

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arxiv 1804.05109 v1 pith:NIJAI5TX submitted 2018-04-13 physics.geo-ph cond-mat.mtrl-sci

classification physics.geo-phcond-mat.mtrl-sci
keywords coreinnerearthhightemperaturesconditionironpressures
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abstract

The crystal structure of iron in the Earth's inner core remains debated. Most recent experiments suggest a hexagonal-close-packed (hcp) phase. In simulations, it has been generally agreed that the hcp-Fe is stable at inner core pressures and relatively low temperatures. At high temperatures, however, several studies suggest a body-centered-cubic (bcc) phase at the inner core condition. We have examined the crystal structure of iron at high pressures over 2 million atmospheres (>200GPa) and at high temperatures over 5000 kelvin in a laser-heated diamond cell using microstructure analysis combined with $\textit{in-situ}$ x-ray diffraction. Experimental evidence shows a bcc-Fe appearing at core pressures and high temperatures, with an hcp-bcc transition line in pressure-temperature space from about 95$\pm$2GPa and 2986$\pm$79K to at least 222$\pm$6GPa and 4192$\pm$104K. The trend of the stability field implies a stable bcc-Fe at the Earth's inner core condition, with implications including a strong candidate for explaining the seismic anisotropy of the Earth's inner core.

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  1. Impact of anharmonicity on sound wave velocities at extreme conditions

    cond-mat.mtrl-sci 2019-08 conditional novelty 6.0 of 10

    Anharmonic atomic vibrations reduce the calculated transverse sound-wave velocity in hcp iron at Earth's core conditions by up to about 10 percent, while leaving the longitudinal velocity almost unchanged.

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