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Chemically Induced Transformation of CVD-Grown Bilayer Graphene into Single Layer Diamond

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arxiv 1901.02131 v1 pith:4CCDN63J submitted 2019-01-08 cond-mat.mtrl-sci

Pavel V. Bakharev , Ming Huang , Manav Saxena , Suk Woo Lee , Se Hun Joo , Sung O Park , Jichen Dong , Dulce Camacho-Mojica
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Sunghwan Jin Youngwoo Kwon Mandakini Biswal Feng Ding Sang Kyu Kwak Zonghoon Lee Rodney S. Ruoff
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classification cond-mat.mtrl-sci
keywords graphenediamondinducedsingleab-blgbilayerchemicallyelectron
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Notwithstanding numerous density functional studies on the chemically induced transformation of multilayer graphene into a diamond-like film, a comprehensive convincing experimental proof of such a conversion is still lacking. We show that the fluorination of graphene sheets in Bernal (AB)-stacked bilayer graphene (AB-BLG) grown by chemical vapor deposition on a single crystal CuNi(111) surface triggers the formation of interlayer carbon-carbon bonds, resulting in a fluorinated diamond monolayer (F-diamane). Induced by fluorine chemisorption, the phase transition from AB-BLG to single layer diamond was studied and verified by X-ray photoelectron, ultraviolet photoelectron, Raman, UV-Vis, electron energy loss spectroscopies, transmission electron microscopy, and DFT calculations.

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