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Trends in the valence band electronic structures of mixed uranium oxides

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arxiv 2010.08301 v1 pith:XKYMP2J3 submitted 2020-10-16 physics.chem-ph

classification physics.chem-ph
keywords bandelectronicmixedoxidesrixstechniqueuraniumvalence
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Valence band electronic structure of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, UO3) has been studied by the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and by computational methods. We show here that the RIXS technique and recorded U 5f-O 2p charge transfer excitations can be used to proof the validity of theoretical approximations

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