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Low Temperature Structural Phase Transition in the Perovskite Ba2CaMoO6

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arxiv 2011.00103 v1 pith:Q2XW5FQA submitted 2020-10-30 cond-mat.mtrl-sci

Loi T. Nguyen , Robert J. Cava , Allyson M. Fry-Petit This is my paper · ORCID
classification cond-mat.mtrl-sci
keywords phasetransitionangstromsba2camoo6structuralperovskitetemperatureadopts
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Ba2CaMoO6 was synthesized by solid state method. The crystal structure adopts cubic Fm-3m space group at room temperature with lattice parameters of 8.378231(5) {angstroms}. Upon cooling, Ba2CaMoO6 was determined to have a structural phase transition to tetragonal I4/m (a=5.905763(6) {angstroms} and c=8.38817(1) {angstroms}) around 200 K. The phase transition was probed structurally by synchrotron and neutron diffraction and thermodynamically by specific heat and differential scanning calorimetry measurement. This structural phase transition will deepens our understanding of the perovskite family especially the formation of perovskites that break corner sharing networks.

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