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Particle conservation in the single-particle Green's function

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arxiv 2101.00704 v1 pith:73TR4XTB submitted 2021-01-03 cond-mat.str-el

classification cond-mat.str-el
keywords functionparticlesingle-particleexactgreennumbersenseaddition
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abstract

We argue that the exact single-particle Green's function ($G$) in quantum many-body theory does not conserve particle number because the single-particle basis is incomplete. We conclude that the exact $G$ is not a probability amplitude and is not $\Phi$-derivable in the Kadanoff-Baym sense. This sets up a number of inconsistencies involving normalization, the definition of $G$, interpretation of the spectral function, and $\Phi$-derivability. Our result suggests that, in the most general case and in the most literal sense, $G$ is not suitable for computing particle addition/removal spectra.

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Cited by 2 Pith papers

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  1. Quasiparticle wavefunction and its equation of motion

    cond-mat.str-el 2024-12 conditional novelty 6.0 of 10

    A time-dependent quasiparticle wavefunction is defined from the Green function and shown to obey a simple equation of motion, with a model that reproduces sodium and aluminum spectra.

  2. Density-Functional Green Function Theory: Dynamical exchange-correlation field in lieu of self-energy

    cond-mat.str-el 2025-05 conditional novelty 3.0 of 10

    A dynamical exchange-correlation field, defined as the Coulomb potential of a 'dynamical xc hole,' replaces the self-energy in the Green function equation of motion, and cluster-extrapolated approximations reproduce b...

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