Ozone groups and centers of skew polynomial rings

We introduce the ozone group of a noncommutative algebra $A$, defined as the group of automorphisms of $A$ which fix every element of its center. In order to initiate the study of ozone groups, we study PI skew polynomial rings, which have long proved to be a fertile testing ground in noncommutative algebra. Using the ozone group and other invariants defined herein, we give explicit conditions for the center of a PI skew polynomial to be Gorenstein (resp. regular) in low dimension.