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Atomic Cluster Expansion without Self-Interaction

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arxiv 2401.01550 v2 pith:ZBXWA75J submitted 2024-01-03 math.NA cs.NAphysics.comp-ph

classification math.NAcs.NAphysics.comp-ph
keywords expansionclusteratomicmodelself-interactionachievedallowinganalyze
verification ladder T0 review T1 audit T2 compute T3 formal
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The Atomic Cluster Expansion (ACE) (Drautz, Phys. Rev. B 99, 2019) has been widely applied in high energy physics, quantum mechanics and atomistic modeling to construct many-body interaction models respecting physical symmetries. Computational efficiency is achieved by allowing non-physical self-interaction terms in the model. We propose and analyze an efficient method to evaluate and parameterize an orthogonal, or, non-self-interacting cluster expansion model. We present numerical experiments demonstrating improved conditioning and more robust approximation properties than the original expansion in regression tasks both in simplified toy problems and in applications in the machine learning of interatomic potentials.

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Cited by 2 Pith papers

Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score. Full citation record

  1. On the Dimension-Free Approximation of Deep Neural Networks for Symmetric Korobov Functions

    cs.LG 2025-11 conditional novelty 7.0 of 10

    Symmetric squared-ReLU networks approximate symmetric Korobov functions at rate O(m^{-1}) with a dimension-independent prefactor, and gradient-based learning achieves M^{-2/3} generalization error.

  2. A Study on the Fine-Tuning Performance of Universal Machine-Learned Interatomic Potentials (U-MLIPs)

    physics.comp-ph 2025-06 conditional novelty 4.0 of 10

    Fine-tuning universal MACE potentials on targeted datasets generally improves accuracy and convergence speed, though data selection, not the foundation model alone, determines success.

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