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REVIEW 3 major objections 4 minor 138 references

Eigenstate Preparation on Quantum Computers

T0 review · 3 major / 4 minor · reviewed 2026-08-11 · deepseek-v4-flash

Pith's one-line read This thesis argues that maximizing the Rodeo algorithm's success probability, rather than minimizing energy, prepares eigenstates with higher fidelity on shallow quantum circuits and also reaches excited states.

desk verdict Genuinely new VRA algorithm with clean math, but its central scalability claim currently rests on noiseless simulations with an idealized energy target; the hardware demos are real. read the letter →

arxiv 2412.15081 v1 pith:EHRZUIZP submitted 2024-12-19 quant-ph

classification quant-ph PACS 03.67.Lx03.67.-a
keywords eigenstatepreparationRodeoalgorithmvariationalquantumeigensolverQAOAadiabaticevolutionoptimalcontrolsimulationNISQ
verification ladder T0 review T1 audit T2 compute T3 formal

The pith

A machine-rendered reading of the paper's core claim, the machinery that carries it, and where it could break.

The reading

Solving eigenvalue problems—finding the eigenstates and energies of a Hamiltonian—is the bottleneck for quantum simulation of nuclei and molecules. This thesis proposes a practical route through three quantum algorithms: adiabatic evolution with optimal control, the Rodeo algorithm, and the Variational Rodeo Algorithm (VRA). The central claim is that VRA, which uses the Rodeo success probability as its cost function, prepares eigenstates more faithfully than energy minimization when the variational circuit is too shallow to reach the exact ground state, and that it can target excited states by shifting the Rodeo energy window. If correct, this gives near-term quantum computers a concrete way to turn low-depth circuits into high-fidelity eigenstates, a prerequisite for simulating nuclear structure and reactions.

What carries the argument

The central object is the Rodeo success probability used as a variational cost function (Equation 5.13). The circuit is: prepare a parameterized ansatz, then for each of $M$ Rodeo cycles apply a Hadamard to an ancilla, perform a controlled time evolution $e^{-iH_{\text{obj}}t}$, apply a phase rotation $e^{iEt}$, apply another Hadamard, and measure the ancilla. The probability that all ancilla measurements give $|0\rangle$ is $$\sum_n |c_n|^2\left[\frac{1+$e^{{-(E_n-E)^2\sigma^2/2}}$}{2}\right]^M,$$ which exponentially suppresses eigenstates whose energies lie outside a window around $E$. Maximizing this probability is the mechanism that steers the parameterized circuit toward a chosen eigenstate, and it is what distinguishes VRA from energy-minimization approaches.

What would settle it

Run VRA on a real noisy device for a random 6-qubit Hamiltonian, using only an estimated energy (for example from a prior VQE calculation) as the Rodeo target, and compare the measured ground-state overlap and success probability against QAOA energy minimization with equal circuit depth. If the VRA advantage disappears under device noise, or if the optimized parameters fail to increase the measured Rodeo success probability relative to the simulated value predicted by Equation 5.13, the central claim is not borne out on hardware.

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Extended reading notes

Core claim

The paper's central proposal is the Variational Rodeo Algorithm: append a Rodeo circuit to a parameterized state-preparation ansatz (here QAOA) and classically optimize the ansatz parameters to maximize the probability that every Rodeo ancilla measurement returns $|0\rangle$, i.e. to minimize $1-P_N$. For a state $|\psi\rangle=\sum_n c_n|E_n\rangle$ of the object Hamiltonian and a Rodeo energy parameter $E$, the success probability is $$P_\psi=\sum_n |c_n|^2\left[\frac{1+$e^{{-(E_n-E)^2\sigma^2/2}}$}{2}\right]^M.$$ Because each eigenstate's contribution is damped by a Gaussian factor centered at $E$, maximizing this probability concentrates the state on the eigenstate with eigenvalue closest to $E$. In noiseless simulations on random 6- and 10-qubit Hamiltonians, the paper finds that this cost function drives the QAOA output toward the targeted eigenstate—including excited states—and that for shallow circuits (12–20 parameters) it reaches higher ground-state overlap than energy minimization. The same simulations show that using VRA as a fine-tuning step after energy minimization improves overlap in cases where the variational principle is not in effect. The paper also demonstrates the two building blocks: adiabatic evolution with optimal-control custom gates reaches roughly 95% fidelity in emulations against about 60–85% on cloud processors, and the Rodeo algorithm recovers single-qubit eigenvalues to 0.08% relative error on hardware.

Load-bearing premise

The claim that VRA is an effective eigenstate-preparation method rests on the assumption that the noiseless success probability of the Rodeo circuit is a faithful stand-in for real-device performance, since all VRA results come from exact classical simulations and the ground-state tests supply the exact ground-state energy as input.

Editorial extensions

If this is right

  • VRA turns an arbitrary parameterized ansatz into an eigenstate filter: by choosing the Rodeo energy $E$, the same circuit can be steered to the ground state or to a specific excited state.
  • For shallow QAOA circuits, optimizing the Rodeo success probability yields higher ground-state overlap than energy minimization, so VRA can replace or follow VQE/QAOA optimization.
  • The success probability is estimated by counting ancilla measurement outcomes, avoiding the need for full Hamiltonian expectation-value estimation in the optimization loop.
  • Rodeo's exponential suppression of off-target eigenstates means the added cost of the Rodeo tail grows only logarithmically with the desired eigenstate purity, making the hybrid approach compatible with NISQ-era circuit depths.

Reading between the lines

Editorial extensions of the paper, not claims the author makes directly.

  • Editorial inference: the same cost function could be applied to any parameterized ansatz beyond QAOA, such as hardware-efficient circuits, as long as controlled time evolution under $H_{\text{obj}}$ is available; the paper only tests QAOA.
  • Editorial inference: because the Rodeo success probability is a binary-measurement count rather than a signed energy expectation, it may be more robust to certain systematic errors; this is testable by comparing gradient noise under a depolarizing noise model.
  • Editorial inference: VRA's ability to target excited states, combined with the Hellmann-Feynman technique demonstrated for the Rodeo algorithm, could enable spectrum and observable calculations without orthogonality-constrained excited-state variational methods.
  • Editorial inference: the noiseless-proxy assumption will be the first thing to break as system size grows: the exact energy input $E_0$ used in the tests must in practice be replaced by an estimate, and error in that estimate should degrade the overlap advantage.
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Editorial analysis

A structured set of objections, weighed in public.

Desk editor's note, referee report, and a circularity audit.

Referee Report

3 major / 4 minor

Summary. This thesis (arXiv:2412.15081) develops and tests three quantum algorithms for eigenstate preparation: adiabatic evolution with optimal control (Chapter 3), the Rodeo Algorithm (RA, Chapter 4), and the novel Variational Rodeo Algorithm (VRA, Chapter 5). The RA section derives the success probability for N cycles with Gaussian-sampled time parameters, demonstrates eigenvalue scans and eigenstate preparation on a single-qubit Hamiltonian on IBM Casablanca hardware (achieving 0.08% relative energy error with measurement-error mitigation), and argues for an exponential advantage over phase estimation and adiabatic evolution. The VRA section proposes maximizing the RA success probability as a variational cost function for QAOA parameters, derives the gradient structure of three cost functions, and reports noiseless classical simulations on random 6- and 10-qubit Hamiltonians showing that VRA prepares ground and excited states with higher fidelity than energy minimization for low-depth QAOA circuits.

Significance. The strengths of the manuscript are the clean analytic derivations: the RA success probability (Eqs. 4.5–4.10) and the VRA cost-function gradients (Section 5.2) are carefully derived from the initial-state overlap without assuming knowledge of the target eigenstate. The hardware demonstration of RA (Section 4.2.2) is a concrete, reproducible experiment with measurement-error mitigation, and the 0.08% eigenvalue error is a useful benchmark. The VRA idea is a plausible and interesting extension that directly addresses RA's dependence on initial-state overlap, and the comparison of energy minimization versus overlap maximization is informative. However, the central claim that VRA 'allows for better scalability' is currently supported only by noiseless simulations with the exact ground-state energy injected into the cost function; the numerical evidence does not yet cover the operational conditions of a near-term device.

major comments (3)
  1. [Section 5.3.2, Eq. (5.13)] The VRA ground-state comparison sets the target energy E in Eq. (5.13) to the exact ground-state energy E0, a quantity that is not known in practice for the systems that motivate the algorithm. Because the abstract claims better scalability under realistic conditions, this oracle-like input is load-bearing; the manuscript does not test how VRA performs when E is only known approximately, which would require energy scanning or a broader energy filter and could substantially reduce the reported success probabilities.
  2. [Section 5.3 (including 5.3.1 and 5.3.2)] All VRA results are obtained by classically computing exact final states and evaluating the noiseless expectation value P_N from Eq. (5.13); no noisy circuit simulation, finite-shot sampling, or hardware experiment is presented for VRA. Since the VRA circuit appends the RA controlled time evolutions and an ancilla register to the QAOA ansatz, the circuit depth is at least double that of QAOA alone, so the noiseless advantage shown in Figures 5.3 and 5.4 could vanish or reverse under gate errors, decoherence, and the post-selection cost of conditioning on all ancilla successes. A benchmark with a standard noise model and finite shots is needed to support the claim that VRA allows better scalability on near-term devices.
  3. [Section 4.1.1, Eqs. (4.9)–(4.11)] The claimed exponential speedup of RA over phase estimation and adiabatic evolution for eigenstate preparation is based purely on scaling in the residual error Δ, omitting the total coherent evolution time per preparation, which grows with the number of cycles N and the standard deviation σ of the time parameters. The complexity comparison should include these resources, along with the cost of implementing the controlled time evolution (e.g., Trotterization), before concluding that RA is exponentially more efficient for large systems; this is a load-bearing point for the motivation of VRA.
minor comments (4)
  1. [Section 3.3.1.1, Eq. (3.14)] The notation "||c|^2_exp>" in the confusion-matrix equation is malformed; it should read "|c^2_exp>" or similar, with the superscript applied to the probability vector.
  2. [Section 5.2, Eq. (5.13)] The definition of P_ψ uses M for the number of cycles, while the surrounding text and figures (e.g., Figure 5.3) use N; unify the notation to avoid confusion.
  3. [Section 4.2.2.3] The phrase "ascanwith" appears to be a typo; it should read "a scan with".
  4. [Chapter 3, Figures 3.2 and 3.3] The captions state that the figures are reused from [31] but do not specify the source or permission; for an arXiv posting, this is acceptable but should be clarified if the manuscript is submitted elsewhere.

Circularity Check

2 steps flagged · score 4.0 of 10

VRA's cost function is a direct overlap proxy, so the eigenstate-preparation outcome is partly definitional; the comparison with energy minimization retains independent content.

  1. self definitional [Section 5.2.3, Eq. (5.13); Section 5.3.2, Simulation Method 2]
    "Before performing optimizations, we directly solve for the eigenvectors |E_k⟩ of H_obj and use the ground-state energy E0 as the target energy parameter in Equation 5.13 for P_N along with a σ value of 10. ... We note that the plots produced by VRA for ground state overlap and P_N are similar because, in this example, the RA parameters E = E0 and σ = 10 make it so that the energy filter of the RA is smaller than the energy gap to the first excited state."

    With E = E0 and σ large relative to the gap, the Gaussian weight in Eq. (5.13) is approximately 1 for the ground state and approximately 0 for all other eigenstates, so P_N reduces essentially to the ground-state overlap |c_0|^2. Thus VRA's cost function is a direct, reweighted estimate of the very quantity used to report success. Optimizing this cost and then reporting high ground-state overlap or high RA success probability is a tautology: the optimizer is maximizing the metric being measured. The claimed advantage over energy minimization is not fully circular because it depends on the optimization landscape, but the eigenstate-preparation result is built into the objective.

  2. self definitional [Section 5.3.1, Simulation Method 1 (Figure 5.2)]
    "Since VRA aims to maximize the success probability of the Rodeo algorithm, the cost function to minimize is defined as 1−P_N. ... for each value of E used in the VRA cost functions, a red dot is placed at the y coordinate corresponding to the eigenstate that had the highest overlap, which was the one with the eigenvalue closest to E in every case."

    The claimed demonstration of excited-state preparation is forced by the cost function's definition. Equation (5.13) weights each eigenstate by a Gaussian centered at E, so the eigenstate nearest E automatically receives the largest weight and, after optimization, the largest overlap. Observing that VRA selects the eigenstate closest to E is therefore a restatement of the objective rather than an independent finding about the algorithm's excited-state capability.

full rationale

The Rodeo Algorithm analysis in Chapter 4 (Eqs. 4.1-4.10) is a self-contained state-vector derivation: the success-probability formula is computed from the circuit and initial-state overlaps, not assumed from the target eigenstate, so that part is not circular. The load-bearing circularity is in Chapter 5: VRA chooses the RA success probability P_N (Eq. 5.13) as its cost function, and P_N is by construction a weighted sum of eigenstate overlaps. When the numerical benchmark supplies E = E0 exactly and σ is large relative to the gap, P_N becomes essentially the ground-state overlap |c_0|^2, as the paper itself notes. Reporting high P_N and high overlap after optimizing this cost is therefore a direct consequence of the objective. The excited-state 'demonstration' is similarly forced because Eq. (5.13) assigns the largest weight to the eigenstate closest to E. However, the comparison of VRA with energy minimization (Figure 5.3) is not fully circular: that maximizing overlap can beat minimizing energy for low-depth QAOA is a landscape result with independent content. No load-bearing self-citation was found: citations [30,105] underpin the RA, but the thesis re-derives the relevant formulas. The absence of a noise model and the use of the exact E0 oracle are real scalability concerns, but they are not circularity. Score 4 reflects partial, not complete, circularity because the central VRA-versus-VQE claim retains independent numerical content.

Assumptions & free parameters 7 free parameters · 6 assumptions · 0 invented entities

The central new result of the thesis, the Variational Rodeo Algorithm, rests on the Rodeo success probability formula (Eq. 5.13), which is derived from the Born rule and Gaussian averaging. The numerical evidence for VRA is obtained from noiseless statevector simulation, and the key ground-state comparison uses the exact ground-state energy as input. No new physical entities are introduced.

free parameters (7)
  • transmon anharmonicity alpha = 200 MHz
    Chosen model parameter for the two-transmon Hamiltonian in Section 3.3.2; the optimal-control emulation results depend on it.
  • transmon coupling strength g = 3 MHz
    Chosen model parameter for capacitive crosstalk in Section 3.3.2; affects the gate optimization and emulation.
  • pulse penalty cutoff epsilon_cut = 30 MHz
    Hyperparameter in the GRAPE objective function (Eq. 3.28) that limits pulse amplitudes; chosen for all optimizations.
  • pulse penalty constants n and chi = n=3, chi=1e-3
    Hyperparameters in Eq. 3.28 governing the penalty term for large pulse amplitudes.
  • RA time parameter standard deviation sigma = varies across demonstrations (2, 5, 7, 10, 12)
    Standard deviation of Gaussian sampling for time evolutions; controls the energy filter width and is chosen by hand for each experiment.
  • number of RA cycles N = varies (3, 4, 6, 9)
    Number of rodeo cycles; larger N gives better filtering but deeper circuits; chosen per experiment.
  • QAOA parameter count = 12, 16, 20
    Number of tunable parameters in the QAOA ansatz used in VRA simulations (Section 5.3).
assumptions (6)
  • standard math The adiabatic theorem guarantees that a system initialized in an eigenstate remains in the instantaneous eigenstate for sufficiently slow evolution with a spectral gap.
    Used throughout Chapter 3 to justify eigenstate preparation via slow Hamiltonian interpolation.
  • standard math Born rule and projective measurement statistics.
    Used to derive success probabilities for the Rodeo Algorithm in Equations 4.5 through 4.9.
  • standard math Unitary time evolution and the Trotter-Suzuki decomposition.
    Used to discretize adiabatic evolution (Eq. 3.12) and to implement controlled time evolution in the Rodeo Algorithm.
  • standard math The Gaussian averaging identity that yields the exponential suppression in Eq. 4.10.
    Derived in Section 4.1.1 and used as the basis for RA complexity claims and the VRA cost function.
  • standard math The variational principle for energy expectation values.
    Used in Section 5.2.1 to establish the baseline energy-minimization cost function.
  • domain assumption Random Hermitian Hamiltonians with no degenerate eigenstates are representative test cases for variational algorithms.
    Section 5.3 uses randomly generated Hamiltonians to benchmark VRA against QAOA; the generality of the conclusions depends on this representativeness.

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Cite this review

Pith. "Pith review of Eigenstate Preparation on Quantum Computers." pith.science (2026). https://pith.science/paper/EHRZUIZP

@misc{pith2026241215081,
  author       = {Pith},
  title        = {Pith review of: Eigenstate Preparation on Quantum Computers},
  year         = {2026},
  howpublished = {\url{https://pith.science/paper/EHRZUIZP}},
  note         = {Machine review of arXiv:2412.15081}
}
read the original abstract

This thesis investigates quantum algorithms for eigenstate preparation, with a focus on solving eigenvalue problems such as the Schrodinger equation by utilizing near-term quantum computing devices. These problems are ubiquitous in several scientific fields, but more accurate solutions are specifically needed as a prerequisite for many quantum simulation tasks. To address this, we establish three methods in detail: quantum adiabatic evolution with optimal control, the Rodeo Algorithm, and the Variational Rodeo Algorithm. The first method explored is adiabatic evolution, a technique that prepares quantum states by simulating a quantum system that evolves slowly over time. The adiabatic theorem can be used to ensure that the system remains in an eigenstate throughout the process, but its implementation can often be infeasible on current quantum computing hardware. We employ a unique approach using optimal control to create custom gate operations for superconducting qubits and demonstrate the algorithm on a two-qubit IBM cloud quantum computing device. We then explore an alternative to adiabatic evolution, the Rodeo Algorithm, which offers a different approach to eigenstate preparation by using a controlled quantum evolution that selectively filters out undesired components in the wave function stored on a quantum register. We show results suggesting that this method can be effective in preparing eigenstates, but its practicality is predicated on the preparation of an initial state that has significant overlap with the desired eigenstate. To address this, we introduce the novel Variational Rodeo Algorithm, which replaces the initialization step with dynamic optimization of quantum circuit parameters to increase the success probability of the Rodeo Algorithm. The added flexibility compensates for instances in which the original algorithm can be unsuccessful, allowing for better scalability.

Figures

Figures reproduced from arXiv: 2412.15081 by the authors.

Figure 2
Figure 2. The Bloch sphere representing the state of a single qubit as coordinates on a sphere [PITH_FULL_IMAGE:figures/full_fig_p022_2.png] view at source ↗
Figure 2
Figure 2. A basic quantum circuit diagram for creating a Bell state. The initial state on the left is [PITH_FULL_IMAGE:figures/full_fig_p026_2.png] view at source ↗
Figure 2.1
Figure 2.1. 2. The gates in these diagrams are applied sequentially from left to right on the quantum [PITH_FULL_IMAGE:figures/full_fig_p026_2_1.png] view at source ↗
Figures from the paper (22 more)
Figure 2
Figure 2. Figure 2: A circuit diagram for a Controlled-U gate. [PITH_FULL_IMAGE:figures/full_fig_p029_2.png]
Figure 3
Figure 3. Figure 3: (Figure reused from [31]) of the fidelity between the device state and the ground state [PITH_FULL_IMAGE:figures/full_fig_p059_3.png]
Figure 3
Figure 3. Figure 3: (Figure reused from [31]) Decomposition of the first short-time propagator in [PITH_FULL_IMAGE:figures/full_fig_p061_3.png]
Figure 3
Figure 3. Figure 3: (Figure reused from [31]) Schematic depiction of [PITH_FULL_IMAGE:figures/full_fig_p063_3.png]
Figure 3
Figure 3. Figure 3: (Figure reused from [31]) First 100 ns of control pulses with lengths [PITH_FULL_IMAGE:figures/full_fig_p068_3.png]
Figure 3
Figure 3. Figure 3: (Figure reused from [31]) Adiabatic evolution of [PITH_FULL_IMAGE:figures/full_fig_p071_3.png]
Figure 3
Figure 3. Figure 3: (Figure reused from [31]) Combination of simultaneous U3 gates [circuit [PITH_FULL_IMAGE:figures/full_fig_p074_3.png]
Figure 3
Figure 3. Figure 3: (Figure reused from [31]) A comparison of the emulated outputs of the adiabatic [PITH_FULL_IMAGE:figures/full_fig_p076_3.png]
Figure 3
Figure 3. Figure 3: (Figure reused from [31]) Mean error in measured occupation probabilities as a [PITH_FULL_IMAGE:figures/full_fig_p077_3.png]
Figure 3
Figure 3. Figure 3: (Figure reused from [31]) Evolution of [PITH_FULL_IMAGE:figures/full_fig_p078_3.png]
Figure 4
Figure 4. Figure 4: One cycle of the Rodeo algorithm. Additional copies of this circuit can be appended to [PITH_FULL_IMAGE:figures/full_fig_p082_4.png]
Figure 4
Figure 4. Figure 4: (Figure reused from [30]) Initial-state spectral function for the Heisenberg model. [PITH_FULL_IMAGE:figures/full_fig_p088_4.png]
Figure 4
Figure 4. Figure 4: (Figure reused from [30]) Logarithm of the wave function error versus the total [PITH_FULL_IMAGE:figures/full_fig_p090_4.png]
Figure 4
Figure 4. Figure 4: (Figure reused from [105]) Sequential scans of the energy. Each bin represents a [PITH_FULL_IMAGE:figures/full_fig_p093_4.png]
Figure 4
Figure 4. Figure 4: , the energy eigenvalues of [PITH_FULL_IMAGE:figures/full_fig_p094_4.png]
Figure 4
Figure 4. Figure 4: (Figure reused from [105]) Energy scans for [PITH_FULL_IMAGE:figures/full_fig_p095_4.png]
Figure 4
Figure 4. Figure 4: (Figure reused from [105]) Eigenvalues [PITH_FULL_IMAGE:figures/full_fig_p096_4.png]
Figure 5
Figure 5. Figure 5: A circuit diagram of a QAOA circuit with objective Hamiltonian [PITH_FULL_IMAGE:figures/full_fig_p107_5.png]
Figure 5
Figure 5. Figure 5: An analysis of the final states [PITH_FULL_IMAGE:figures/full_fig_p109_5.png]
Figure 5
Figure 5. Figure 5: A comparison of the VRA (left) and VQE (right) cost functions for BFGS [PITH_FULL_IMAGE:figures/full_fig_p111_5.png]
Figure 5
Figure 5. Figure 5: Results for a two-step BFGS optimization of a 12 parameter 6 qubit QAOA circuit with [PITH_FULL_IMAGE:figures/full_fig_p113_5.png]
Figure 5
Figure 5. Figure 5: A comparison of values of the two cost functions, [PITH_FULL_IMAGE:figures/full_fig_p114_5.png]

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Pith tools

Reviewed August 11, 2026 · model on record in the stance chip above.