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Orbital-selective band modifications in a charge-ordered kagome metal LuNb$_6$Sn$_6$
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abstract
The origin of the charge order in kagome lattice materials has attracted great interest due to the unique electronic structure features connected to kagome networks and the interplay between electron and lattice degrees of freedom. Recently, compounds with composition $Ln$Nb$_6$Sn$_6$ ($Ln$ = Ce-Nd, Sm, Gd-Tm, Lu, Y) appear as a new family of kagome metals, structurally analogous to $R$V$_6$Sn$_6$ ($R$ = Sc, Y, or rare earth) systems. Among them, LuNb$_6$Sn$_6$ emerges as a novel material hosting charge density wave (CDW) with a $\sqrt{3}$ $\times$ $\sqrt{3}$ $\times$ $3$ wave vector, akin to that in ScV$_6$Sn$_6$. Here, we employ high-resolution angle-resolved photoemission spectroscopy, scanning tunneling microscopy, and density functional theory calculations to systematically investigate the electronic properties of LuNb$_6$Sn$_6$. Our observation reveals the characteristic band structures of the "166" kagome system. A charge instability driven by Fermi surface nesting is decisively ruled out through an analysis of the interactions between van Hove singularities. Across the CDW transition, we observe orbital-selective band modifications, with noticeable evolutions of Lu 5$d$ and Sn 5$p$ electrons, while Nb 4$d$ electrons exhibit minimal change, suggesting that the Lu and Sn sites other than the Nb kagome lattice play a key role in the formation of CDW. Our findings substantiate a universal lattice-driven CDW mechanism rather than a charge-instability-driven one in the "166" kagome compounds, making it a distinct material class compared to other charge-ordered kagome systems, such as $A$V$_3$Sb$_5$ ($A$ = K, Rb, Cs) and FeGe.
Forward citations
Cited by 2 Pith papers
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Fermiology of the kagome compound LuNb6Sn6 probed by de Haas-van Alphen oscillations
LuNb6Sn6's Fermi surface consists of two small ellipsoidal pockets; the low-frequency pocket shows a nontrivial Berry phase, and the CDW transition at 85 K is first-order.
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Quantum oscillations and Dirac dispersion in tunable kagome lattice Lu$_{1-y}$Y$_y$(Nb$_{1-x}$Ta$_x$)$_6$Sn$_6$
Alloying in Lu1-yYy(Nb1-xTax)6Sn6 suppresses CDW order while quantum oscillations show shrinking Fermi surfaces and effective-mass scaling consistent with Dirac dispersion.
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