pith. sign in

arxiv: 2605.18400 · v1 · pith:RRHCKAB2new · submitted 2026-05-18 · ❄️ cond-mat.mtrl-sci

Metastable Cu_(1-x)CrTe₂ -- Completing the copper chromium delafossite series through soft chemistry

Kai D. R\"oseler , Geo Sciarini , Felix Eder , Samuel Moody , Vladimir Pomjakushin , Fabian O. von Rohr This is my paper

Pith reviewed 2026-05-20 09:24 UTC · model grok-4.3

classification ❄️ cond-mat.mtrl-sci
keywords delafossitemetastable phasecation exchangeantiferromagnetismtelluridesolvothermal synthesistopochemical reactioncopper chromium compound
0
0 comments X

The pith

Metastable Cu1-xCrTe2 is made by low-temperature cation exchange and orders antiferromagnetically at 239 K.

A machine-rendered reading of the paper's core claim, the machinery that carries it, and where it could break.

The paper shows that the missing telluride member of the CuCrX2 series can be prepared as a metastable phase only through a solvothermal cation exchange reaction near 90 degrees Celsius. This low-temperature topochemical route starts from the potassium analogue and inserts copper while preserving the layered structure. The resulting material undergoes a magnetostructural transition to an antiferromagnetic state at a Néel temperature of 239 K, which stands out as high among related A Cr Te2 compounds. A reader would care because the work illustrates how soft chemistry can reach copper(I)-containing tellurides that conventional high-temperature solid-state reactions cannot produce, thereby completing a structural family for further study.

Core claim

Cu1-xCrTe2 (x approximately 0.3) forms only within a narrow temperature window near 90 degrees Celsius by solvothermal cation exchange of K1-xCrTe2 (x approximately 0.3) and CuBr. The phase undergoes a magnetostructural transition to an antiferromagnetic state at TN equal to 239 K, a Néel temperature high relative to other A Cr Te2 phases and comparable to that of ferromagnetic fully deintercalated CrTe2. Cu1-xCrTe2 is metastable and decomposes at temperatures as low as 250 degrees Celsius to form the spinel CuCr2Te4.

What carries the argument

Solvothermal cation exchange reaction performed in a narrow temperature window near 90 degrees Celsius that inserts copper into the layered potassium chromium telluride precursor while keeping the structure intact.

Load-bearing premise

The cation exchange reaction produces a phase-pure metastable product that retains the layered structure without defects or impurities that would alter the observed magnetic transition temperature.

What would settle it

Detailed X-ray diffraction and magnetic susceptibility measurements on the product that reveal major impurity phases or a Néel temperature far from 239 K, or the inability to form the phase at all under the reported solvothermal conditions, would falsify the central claim.

read the original abstract

In the layered copper chromium dichalcogenide series CuCr$X_2$, the oxide, the sulfide, and the selenide analogues have been reported, but the telluride CuCrTe$_2$ has remained unsynthesized so far. Here, we report the synthesis of Cu$_{1-x}$CrTe$_2$ ($x \approx 0.3$), which forms only within a narrow temperature window near 90 {\deg}C by solvothermal cation exchange of K$_{1-x}$CrTe$_2$ ($x \approx 0.3$) and CuBr. Cu$_{1-x}$CrTe$_2$ undergoes a magnetostructural transition to an antiferromagnetic state at $T_\mathrm{N}=239$ K, a N\'eel temperature that is high relative to other $A$CrTe$_2$ phases and comparable to that of ferromagnetic, fully-deintercalated CrTe$_2$. Cu$_{1-x}$CrTe$_2$ is metastable and decomposes at temperatures as low as 250 {\deg}C to form spinel CuCr$_2$Te$_4$. These results highlight the importance of low-temperature topochemical routes for accessing metastable Cu(I)-containing tellurides that are inaccessible by conventional solid-state synthesis.

Editorial analysis

A structured set of objections, weighed in public.

Desk editor's note, referee report, simulated authors' rebuttal, and a circularity audit. Tearing a paper down is the easy half of reading it; the pith above is the substance, this is the friction.

Referee Report

2 major / 2 minor

Summary. The manuscript reports the synthesis of metastable Cu_{1-x}CrTe_2 (x ≈ 0.3) via solvothermal cation exchange of K_{1-x}CrTe_2 with CuBr at ~90 °C, completing the CuCrX_2 delafossite series for X=Te. The phase is claimed to undergo a magnetostructural transition to an antiferromagnetic state at T_N=239 K (high relative to other A Cr Te_2 phases and comparable to CrTe_2), and to decompose above 250 °C into spinel CuCr_2Te_4. The work emphasizes low-temperature topochemical routes for accessing metastable Cu(I)-containing tellurides.

Significance. If the phase purity and intrinsic nature of the 239 K transition are confirmed, this completes the copper chromium dichalcogenide series and provides a clear demonstration of soft-chemistry access to metastable phases inaccessible by conventional solid-state methods. The relatively high Néel temperature and metastability are of interest for layered magnetic materials, and the explicit comparison to other A Cr Te_2 and CrTe_2 phases strengthens the context.

major comments (2)
  1. Results section on magnetic characterization: the assignment of the 239 K transition as intrinsic to phase-pure Cu_{1-x}CrTe_2 requires quantitative evidence (e.g., Rietveld refinement statistics, impurity phase fractions <1%, or magnetization vs. field loops) that the cation-exchange product contains no residual K, Br incorporation, or Cr-rich minority phases capable of shifting or pinning T_N; without these data the high T_N relative to other A Cr Te_2 phases cannot be unambiguously attributed to the target delafossite.
  2. Experimental methods and Figure on structural characterization: the narrow 90 °C temperature window and x ≈ 0.3 deficiency are central to the metastability claim, yet the manuscript does not report post-exchange elemental analysis (EDS or ICP) or local probe data (e.g., EXAFS or NMR) to confirm complete Cu insertion and absence of stacking faults that could alter the magnetostructural coupling.
minor comments (2)
  1. Abstract: the LaTeX formatting artifacts (e.g., {deg}) should be cleaned for the final version.
  2. Discussion: add a brief comparison table of T_N values for all known A Cr Te_2 (A = K, Na, Cu, etc.) to make the “high relative to other phases” statement quantitative.

Simulated Author's Rebuttal

2 responses · 0 unresolved

We thank the referee for their careful review and constructive comments, which have helped us improve the manuscript. We address each of the major comments below.

read point-by-point responses

  1. Referee: Results section on magnetic characterization: the assignment of the 239 K transition as intrinsic to phase-pure Cu_{1-x}CrTe_2 requires quantitative evidence (e.g., Rietveld refinement statistics, impurity phase fractions <1%, or magnetization vs. field loops) that the cation-exchange product contains no residual K, Br incorporation, or Cr-rich minority phases capable of shifting or pinning T_N; without these data the high T_N relative to other A Cr Te_2 phases cannot be unambiguously attributed to the target delafossite.

    Authors: We agree that quantitative evidence for phase purity strengthens the attribution of the transition. The original manuscript reports powder XRD and a single sharp transition at 239 K. In the revised manuscript we have added the Rietveld refinement statistics (including R factors) together with an estimated impurity fraction below 3 % derived from the fit. Isothermal M(H) loops at 300 K and 150 K have also been included to demonstrate the absence of detectable ferromagnetic contributions from possible Cr-rich phases. Residual K or Br below the detection limit of the available bulk measurements cannot be rigorously excluded without new experiments, but the lack of additional magnetic anomalies and the structural consistency support the assignment to the target phase. revision: yes

  2. Referee: Experimental methods and Figure on structural characterization: the narrow 90 °C temperature window and x ≈ 0.3 deficiency are central to the metastability claim, yet the manuscript does not report post-exchange elemental analysis (EDS or ICP) or local probe data (e.g., EXAFS or NMR) to confirm complete Cu insertion and absence of stacking faults that could alter the magnetostructural coupling.

    Authors: The narrow temperature window and nominal x ≈ 0.3 were established by systematic variation of reaction conditions and by refinement of the lattice parameters against the precursor. In the revision we have added a brief description of available post-exchange EDS results confirming Cu incorporation at the expected level and the absence of detectable Br. Advanced local probes such as EXAFS or NMR were not performed in this study; their absence is a limitation. The sharp XRD reflections and the well-defined magnetostructural transition provide supporting (though indirect) evidence against substantial stacking faults, which we now discuss explicitly in the revised text. revision: partial

Circularity Check

0 steps flagged

No circularity: experimental synthesis report with direct observations

full rationale

This is an experimental materials synthesis paper reporting solvothermal cation exchange to produce metastable Cu_{1-x}CrTe_2 and its measured magnetostructural transition at T_N=239 K. There are no derivations, equations, fitted parameters, predictions, or ansatzes. All central claims rest on direct experimental inputs (synthesis conditions, XRD, magnetic measurements) that are independently verifiable by replication and do not reduce to self-citations or internal definitions. The paper is self-contained against external benchmarks with no load-bearing circular steps.

Axiom & Free-Parameter Ledger

0 free parameters · 1 axioms · 0 invented entities

The central claim rests on the domain assumption that low-temperature topochemical cation exchange can kinetically stabilize a metastable delafossite-like phase that is thermodynamically inaccessible by conventional solid-state routes.

axioms (1)
  • domain assumption The potassium precursor K1-xCrTe2 possesses a layered structure suitable for topochemical copper exchange without framework collapse.
    Invoked implicitly when stating that the exchange produces the target Cu1-xCrTe2 phase.

pith-pipeline@v0.9.0 · 5796 in / 1401 out tokens · 59295 ms · 2026-05-20T09:24:45.734547+00:00 · methodology

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.

Reference graph

Works this paper leans on

73 extracted references · 73 canonical work pages

  1. [1]

    Lawrence Bragg , title =

    W. Lawrence Bragg , title =. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science , volume =. 1914 , publisher =. doi:10.1080/14786440908635219 , URL =

    work page doi:10.1080/14786440908635219 1914

  2. [2]

    and Fisher, Ian R

    Canfield, Paul C. and Fisher, Ian R. , title =. Journal of Crystal Growth , volume =. 2001 , type =. doi:https://doi.org/10.1016/S0022-0248(01)00827-2 , url =

    work page doi:10.1016/s0022-0248(01)00827-2 2001

  3. [3]

    and Kong, Tai and Kaluarachchi, Udhara S

    Canfield, Paul C. and Kong, Tai and Kaluarachchi, Udhara S. and Jo, Na Hyun , doi =. Philos. Mag. , keywords =

    work page

  4. [4]

    , journal =

    Colominas, C. , journal =. Neutron-Diffraction Investigation of Cu. 1967 , month =. doi:10.1103/PhysRev.153.558 , url =

    work page doi:10.1103/physrev.153.558 1967

  5. [5]

    and Caffrey, David and Shvets, Igor V

    Farrell, Leo and Norton, Emma and Smith, Christopher M. and Caffrey, David and Shvets, Igor V. and Fleischer, Karsten. Synthesis of nanocrystalline Cu deficient CuCrO2 – a high figure of merit p-type transparent semiconductor. J. Mater. Chem. C. 2016. doi:10.1039/C5TC03161C

    work page doi:10.1039/c5tc03161c 2016

  6. [6]

    Angewandte Chemie International Edition , volume=

    A concept for synthesis planning in solid-state chemistry , author=. Angewandte Chemie International Edition , volume=. 2002 , publisher=

    work page 2002

  7. [7]

    and Johnson, David C

    Cordova, Dmitri Leo M. and Johnson, David C. , title =. ChemPhysChem , volume =. doi:https://doi.org/10.1002/cphc.202000199 , url =. https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/cphc.202000199 , abstract =

    work page doi:10.1002/cphc.202000199

  8. [8]

    , title =

    Chattopadhyay, G. , title =. Journal of Phase Equilibria , volume =. 1994 , type =. doi:10.1007/BF02647574 , url =

    work page doi:10.1007/bf02647574 1994

  9. [9]

    Ladder-Like Structural Architecture of Layered Magnetic

    R. Ladder-Like Structural Architecture of Layered Magnetic. Chemistry--A European Journal , pages=. 2026 , publisher=

    work page 2026

  10. [10]

    Gagor and D

    A. Gagor and D. Gnida and A. Pietraszko , keywords =. Order–disorder phenomena in layered CuCrSe2 crystals , journal =. 2014 , issn =. doi:https://doi.org/10.1016/j.matchemphys.2014.03.024 , url =

    work page doi:10.1016/j.matchemphys.2014.03.024 2014

  11. [11]

    TOPAS and TOPAS-Academic: An Optimization Program Integrating Computer Algebra and Crystallographic Objects Written in C++

    Coelho, Alan , title =. Journal of Applied Crystallography , volume =. 2018 , type =. doi:doi:10.1107/S1600576718000183 , url =

    work page doi:10.1107/s1600576718000183 2018

  12. [12]

    Synthesis and anisotropic magnetic properties of

    Witteveen, Catherine and Nocerino, Elisabetta and L. Synthesis and anisotropic magnetic properties of. Journal of Physics: Materials , volume=. 2023 , publisher=

    work page 2023

  13. [13]

    Fang, Yuqiang and Pan, Jie and Zhang, Dongqin and Wang, Dong and Hirose, Hishiro T. and Terashima, Taichi and Uji, Shinya and Yuan, Yonghao and Li, Wei and Tian, Zhen and Xue, Jiamin and Ma, Yonghui and Zhao, Wei and Xue, Qikun and Mu, Gang and Zhang, Haijun and Huang, Fuqiang , title =. Advanced Materials , volume =. doi:https://doi.org/10.1002/adma.2019...

    work page doi:10.1002/adma.201901942

  14. [14]

    and Weht, Ruben and Sulpice, André and Remenyi, Gyorgy and Strobel, Pierre and Gay, Frédéric and Marcus, Jacques and Núñez-Regueiro, Manuel , title =

    Freitas, Daniele C. and Weht, Ruben and Sulpice, André and Remenyi, Gyorgy and Strobel, Pierre and Gay, Frédéric and Marcus, Jacques and Núñez-Regueiro, Manuel , title =. Journal of Physics: Condensed Matter , volume =. 2015 , type =. doi:10.1088/0953-8984/27/17/176002 , url =

    work page doi:10.1088/0953-8984/27/17/176002 2015

  15. [15]

    Physica B Condens

    Rodriguez-Carvajal, J , title =. Physica B Condens. Matter , number =. 1993 , type =

    work page 1993

  16. [16]

    , title =

    Gopalakrishnan, J. , title =. Chemistry of Materials , volume =. 1995 , type =. doi:10.1021/cm00055a001 , url =

    work page doi:10.1021/cm00055a001 1995

  17. [17]

    Zeitschrift für anorganische und allgemeine Chemie , volume =

    Hahn, Harry and Lorent, Christian De , title =. Zeitschrift für anorganische und allgemeine Chemie , volume =. doi:https://doi.org/10.1002/zaac.19572900108 , url =. https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.19572900108 , abstract =

    work page doi:10.1002/zaac.19572900108

  18. [18]

    Zeitschrift für anorganische und allgemeine Chemie , volume =

    Hahn, Harry and De Lorent, Christian , title =. Zeitschrift für anorganische und allgemeine Chemie , volume =. doi:https://doi.org/10.1002/zaac.19552790504 , url =. https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.19552790504 , abstract =

    work page doi:10.1002/zaac.19552790504

  19. [19]

    Journal of the Physical Society of Japan , volume =

    Hatakeda ,Takehiro and Noji ,Takashi and Kawamata ,Takayuki and Kato ,Masatsune and Koike ,Yoji , title =. Journal of the Physical Society of Japan , volume =. 2013 , doi =

    work page 2013

  20. [20]

    and Avdeev, Maxim and Rees, Nicholas H

    Hyde, Penny A. and Avdeev, Maxim and Rees, Nicholas H. and Clarke, Simon J. , title =. Chemistry of Materials , volume =. 2024 , type =. doi:10.1021/acs.chemmater.4c02155 , url =

    work page doi:10.1021/acs.chemmater.4c02155 2024

  21. [21]

    Hyde, P. A. and Cen, J. and Cassidy, S. J. and Rees, N. H. and Holdship, P. and Smith, R. I. and Zhu, B. and Scanlon, D. O. and Clarke, S. J. , title =. Inorganic Chemistry , volume =. 2023 , type =. doi:10.1021/acs.inorgchem.3c01510 , url =

    work page doi:10.1021/acs.inorgchem.3c01510 2023

  22. [22]

    Zagorac, H

    Zagorac, D. and M \" u ller, H. and Ruehl, S. and Zagorac, J. and Rehme, S. Recent developments in the Inorganic Crystal Structure Database: theoretical crystal structure data and related features. Journal of Applied Crystallography. 2019. doi:10.1107/S160057671900997X , url =

    work page doi:10.1107/s160057671900997x 2019

  23. [23]

    Stokes, H. T. and Hatch, D. M. and Campbell, B. J , title =. Journal of Applied Crystallography , volume =. 2006 , type =

    work page 2006

  24. [24]

    Stokes, H. T. and Hatch, D. M. and Campbell, B. J. , title =

    work page

  25. [25]

    , title =

    Kanatzidis, Mercouri G. , title =. Inorganic Chemistry , volume =. 2017 , type =. doi:10.1021/acs.inorgchem.7b00188 , url =

    work page doi:10.1021/acs.inorgchem.7b00188 2017

  26. [26]

    and Grievson, Heather and Steele, Katherine M

    Kelly, Nicola D. and Grievson, Heather and Steele, Katherine M. and da Silva, Ivan and Clarke, Simon J. Chemical and electrochemical lithiation of van der Waals oxytelluride V2Te2O. Dalton Trans. 2025. doi:10.1039/D5DT00159E

    work page doi:10.1039/d5dt00159e 2025

  27. [27]

    A combined experimental and theoretical study of the prototypical polymorphic transformation from marcasite to pyrite FeS2

    Ma, KeYuan and Aschauer, Ulrich and von Rohr, Fabian O. A combined experimental and theoretical study of the prototypical polymorphic transformation from marcasite to pyrite FeS2. Dalton Trans. 2025. doi:10.1039/D4DT03447C

    work page doi:10.1039/d4dt03447c 2025

  28. [28]

    Li, Y. W. and Zheng, H. J. and Fang, Y. Q. and Zhang, D. Q. and Chen, Y. J. and Chen, C. and Liang, A. J. and Shi, W. J. and Pei, D. and Xu, L. X. and Liu, S. and Pan, J. and Lu, D. H. and Hashimoto, M. and Barinov, A. and Jung, S. W. and Cacho, C. and Wang, M. X. and He, Y. and Fu, L. and Zhang, H. J. and Huang, F. Q. and Yang, L. X. and Liu, Z. K. and C...

    work page doi:10.1038/s41467-021-23076-1 2021

  29. [29]

    Ajayan , title =

    Xiao-Chen Liu and Shuyang Zhao and Xueping Sun and Liangzi Deng and Xiaolong Zou and Youcheng Hu and Yun-Xiao Wang and Ching-Wu Chu and Jia Li and Jingjie Wu and Fu-Sheng Ke and Pulickel M. Ajayan , title =. Science Advances , volume =. 2020 , doi =. https://www.science.org/doi/pdf/10.1126/sciadv.aay4092 , abstract =

    work page doi:10.1126/sciadv.aay4092 2020

  30. [30]

    Lotgering and G.H.A.M

    F.K. Lotgering and G.H.A.M. Ferromagnetic Cu1+yCr2Te4 and CuAgyCr2Te4 with metal-excessive spinel structure , journal =. 1971 , issn =. doi:https://doi.org/10.1016/0038-1098(71)90308-5 , url =

    work page doi:10.1016/0038-1098(71)90308-5 1971

  31. [31]

    Meyer, S. F. and Howard, R. E. and Stewart, G. R. and Acrivos, J. V. and Geballe, T. H. , title =. The Journal of Chemical Physics , volume =. 1975 , month =. doi:10.1063/1.430342 , url =

    work page doi:10.1063/1.430342 1975

  32. [32]

    Solid state metathesis reactions as a conceptual tool in the synthesis of new materials

    Meyer, H.-Jürgen. Solid state metathesis reactions as a conceptual tool in the synthesis of new materials. Dalton Trans. 2010. doi:10.1039/C001031F

    work page doi:10.1039/c001031f 2010

  33. [33]

    Materials Park Ohio , pages=

    Binary alloy phase diagrams second edition , author=. Materials Park Ohio , pages=. 1990 , publisher=

    work page 1990

  34. [34]

    V.; Bourhis, L

    Dolomanov, Oleg V. and Bourhis, Luc J. and Gildea, Richard J. and Howard, Judith A. K. and Puschmann, Horst , title =. Journal of Applied Crystallography , volume =. 2009 , type =. doi:doi:10.1107/S0021889808042726 , url =

    work page doi:10.1107/s0021889808042726 2009

  35. [35]

    and Ciesielski, Kamil and Guetari, Weeam and Toberer, Eric and Augustyn, Veronica and Zevalkink, Alexandra , title =

    Rahman, Md Towhidur and Holzapfel, Noah P. and Ciesielski, Kamil and Guetari, Weeam and Toberer, Eric and Augustyn, Veronica and Zevalkink, Alexandra , title =. Chemistry of Materials , volume =. 2025 , type =. doi:10.1021/acs.chemmater.5c01384 , url =

    work page doi:10.1021/acs.chemmater.5c01384 2025

  36. [36]

    Rigaku Oxford Diffraction Ltd, Yarnton, Oxfordshire, England , year =

    Rigaku, Oxford Diffraction , title =. Rigaku Oxford Diffraction Ltd, Yarnton, Oxfordshire, England , year =

    work page

  37. [37]

    Ternary telluride phases crystallizing in the polythermal non-quasi-binary section

    Koneshova, TI and Kudryashov, NI , journal=. Ternary telluride phases crystallizing in the polythermal non-quasi-binary section. 2014 , publisher=

    work page 2014

  38. [38]

    First-principles study of layered antiferromagnetic

    Srivastava, Divya and Tewari, Girish C and Karppinen, Maarit and Nieminen, Risto M , journal=. First-principles study of layered antiferromagnetic. 2013 , publisher=

    work page 2013

  39. [39]

    Journal of Physics D: Applied Physics , volume=

    Review of the thermoelectric properties of layered oxides and chalcogenides , author=. Journal of Physics D: Applied Physics , volume=. 2022 , publisher=

    work page 2022

  40. [40]

    European Journal of Inorganic Chemistry , volume =

    Röseler, Kai Daniel and Eichele, Klaus and Ströbele, Markus and Meyer, Hans-Jürgen , title =. European Journal of Inorganic Chemistry , volume =. doi:https://doi.org/10.1002/ejic.202300713 , url =. https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.202300713 , abstract =

    work page doi:10.1002/ejic.202300713

  41. [41]

    and Witteveen, Catherine and Besnard, Céline and Pomjakushin, Vladimir and Jeschke, Harald O

    Röseler, Kai D. and Witteveen, Catherine and Besnard, Céline and Pomjakushin, Vladimir and Jeschke, Harald O. and von Rohr, Fabian O. , title =. Journal of Materials Chemistry A , abstract =. 2025 , type =. doi:10.1039/D4TA05649C , url =

    work page doi:10.1039/d4ta05649c 2025

  42. [42]

    Rosenberg and A

    M. Rosenberg and A. Knülle and H. Sabrowsky and Chr. Platte , abstract =. Magnetic properties and structure of some ternary chromium chalcogenides with thallium and silver , journal =. 1982 , issn =. doi:https://doi.org/10.1016/0022-3697(82)90124-X , url =

    work page doi:10.1016/0022-3697(82)90124-x 1982

  43. [43]

    Acta Crystallographica Section A , volume =

    Sheldrick, George , title =. Acta Crystallographica Section A , volume =. 2015 , type =. doi:doi:10.1107/S2053273314026370 , url =

    work page doi:10.1107/s2053273314026370 2015

  44. [44]

    Crystal structure refinement with SHELXL

    Sheldrick, George M. Crystal structure refinement with SHELXL. Acta Crystallographica Section C. 2015. doi:10.1107/S2053229614024218 , url =

    work page doi:10.1107/s2053229614024218 2015

  45. [45]

    Shkvarina and Alexey S

    Elena G. Shkvarina and Alexey S. Shkvarin and Alexey A. Titov and Mikhail S. Postnikov and Jasper R. Plaisier and Lara Gigli and Mattia Gaboardi and Alexander N. Titov , abstract =. Thermal stability of the CuCrSe2 , journal =. 2024 , issn =. doi:https://doi.org/10.1016/j.jssc.2023.124497 , url =

    work page doi:10.1016/j.jssc.2023.124497 2024

  46. [46]

    and Schoop, Leslie M

    Aharon, Sigalit and Chatterjee, Sudipta and Yuan, Fang and Carrel, Gabrielle and Xie, Jiaze and Berry, Tanya and Hoff, Brianna L. and Schoop, Leslie M. , title =. Zeitschrift für anorganische und allgemeine Chemie , volume =. doi:https://doi.org/10.1002/zaac.202500098 , url =. https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.202500098 , abstract =

    work page doi:10.1002/zaac.202500098

  47. [47]

    Kinetics and evolution of magnetism in soft-chemical synthesis of

    Song, Xiaoyu and Schneider, Sarah N and Cheng, Guangming and Khoury, Jason F and Jovanovic, Milena and Yao, Nan and Schoop, Leslie M , journal=. Kinetics and evolution of magnetism in soft-chemical synthesis of. 2021 , publisher=

    work page 2021

  48. [48]

    Cuprous delafossites,

    Aanchal Sethi and Dileep Kumar Yadav and Sitharaman Uma , keywords =. Cuprous delafossites,. Ceramics International , volume =. 2022 , issn =. doi:https://doi.org/10.1016/j.ceramint.2022.01.265 , url =

    work page doi:10.1016/j.ceramint.2022.01.265 2022

  49. [49]

    Journal of the American Chemical Society , volume=

    Transitory Topochemical Tailoring of a van der Waals Superconductor , author=. Journal of the American Chemical Society , volume=. 2025 , publisher=

    work page 2025

  50. [50]

    Journal of the American Chemical Society , volume=

    When van Der Waals Met Kagome: A 2D Antimonide with a Vanadium-Kagome Network , author=. Journal of the American Chemical Society , volume=. 2024 , publisher=

    work page 2024

  51. [51]

    Nature Synthesis , volume=

    Galvanic intercalation of molecular cations into van der Waals materials and heterostructures , author=. Nature Synthesis , volume=. 2026 , publisher=

    work page 2026

  52. [52]

    Materials Advances , volume=

    Tuning the magnetic properties of van der Waals materials by intercalation , author=. Materials Advances , volume=. 2024 , publisher=

    work page 2024

  53. [53]

    Nuclear and magnetic spin structure of the antiferromagnetic triangular lattice compound

    Nocerino, Elisabetta and Witteveen, Catherine and Kobayashi, Shintaro and Forslund, Ola Kenji and Matsubara, Nami and Zubayer, Anton and Mazza, Federico and Kawaguchi, Shogo and Hoshikawa, Akinori and Umegaki, Izumi and others , journal=. Nuclear and magnetic spin structure of the antiferromagnetic triangular lattice compound. 2022 , publisher=

    work page 2022

  54. [54]

    Competition between magnetic interactions and structural instabilities leading to itinerant frustration in the triangular lattice antiferromagnet

    Nocerino, Elisabetta and Kobayashi, Shintaro and Witteveen, Catherine and Forslund, Ola K and Matsubara, Nami and Tang, Chiu and Matsukawa, Takeshi and Hoshikawa, Akinori and Koda, Akihiro and Yoshimura, Kazuyoshi and others , journal=. Competition between magnetic interactions and structural instabilities leading to itinerant frustration in the triangula...

    work page 2023

  55. [55]

    Journal of Solid State Chemistry , volume=

    Crystal structures and magnetic structures of some metal (I) chromium (III) sulfides and selenides , author=. Journal of Solid State Chemistry , volume=. 1973 , publisher=

    work page 1973

  56. [56]

    Competition between the direct exchange interaction and superexchange interaction in layered compounds

    Kobayashi, Shintaro and Ueda, Hiroaki and Michioka, Chishiro and Yoshimura, Kazuyoshi , journal=. Competition between the direct exchange interaction and superexchange interaction in layered compounds. 2016 , publisher=

    work page 2016

  57. [57]

    and Skorupskii, Grigorii and Khoury, Jason F

    Song, Xiaoyu and Hoff, Brianna and Singha, Ratnadwip and Stiles, Joseph W. and Skorupskii, Grigorii and Khoury, Jason F. and Cheng, Guangming and Kamm, Franziska and Uzan, Ayelet J. and Dulovic, Stephanie and Wu, Sanfeng and Pielnhofer, Florian and Yao, Nan and Schoop, Leslie M. , title =. Chemistry of Materials , volume =. 2023 , type =. doi:10.1021/acs....

    work page doi:10.1021/acs.chemmater.3c00813 2023

  58. [58]

    Nature Communications , volume =

    Sun, Zhenyu and Su, Yueqi and Zhi, Aomiao and Gao, Zhicheng and Han, Xu and Wu, Kang and Bao, Lihong and Huang, Yuan and Shi, Youguo and Bai, Xuedong and Cheng, Peng and Chen, Lan and Wu, Kehui and Tian, Xuezeng and Wu, Changzheng and Feng, Baojie , title =. Nature Communications , volume =. 2024 , type =. doi:10.1038/s41467-024-48636-z , url =

    work page doi:10.1038/s41467-024-48636-z 2024

  59. [59]

    Structural Modulation and Enhanced Magnetic Ordering in Incommensurate

    Eder, Felix and Witteveen, Catherine and Giannini, Enrico and von Rohr, Fabian O , journal=. Structural Modulation and Enhanced Magnetic Ordering in Incommensurate. 2025 , publisher=

    work page 2025

  60. [60]

    Stoichiometry and Phase Control in

    Eder, Felix and Witteveen, Catherine and Giannini, Enrico and von Rohr, Fabian O , journal=. Stoichiometry and Phase Control in. 2025 , publisher=

    work page 2025

  61. [61]

    Ferromagnetic-phase transition in the spinel-type CuCr2Te4 , journal =

    Takeshi Suzuyama and Junji Awaka and Hiroki Yamamoto and Shuji Ebisu and Masakazu Ito and Takashi Suzuki and Takao Nakama and Katsuma Yagasaki and Shoichi Nagata , keywords =. Ferromagnetic-phase transition in the spinel-type CuCr2Te4 , journal =. 2006 , issn =. doi:https://doi.org/10.1016/j.jssc.2005.10.007 , url =

    work page doi:10.1016/j.jssc.2005.10.007 2006

  62. [62]

    1980 , publisher=

    Van Bruggen, CF and Haange, RJ and Wiegers, GA and De Boer, DKG , journal=. 1980 , publisher=

    work page 1980

  63. [63]

    Soft chemical synthesis of

    Song, Xiaoyu and Cheng, Guangming and Weber, Daniel and Pielnhofer, Florian and Lei, Shiming and Klemenz, Sebastian and Yeh, Yao-Wen and Filsinger, Kai A and Arnold, Craig B and Yao, Nan and others , journal=. Soft chemical synthesis of. 2019 , publisher=

    work page 2019

  64. [64]

    and Tripathi, T

    Tewari, Girish C. and Tripathi, T. S. and Rastogi, A. K. , title =. Journal of Electronic Materials , volume =. 2010 , type =. doi:10.1007/s11664-010-1185-5 , url =

    work page doi:10.1007/s11664-010-1185-5 2010

  65. [65]

    Synthesis, Characterization, and Magnetic Properties of Layered Transition Metal Dichalcogenides and Their Delafossite-Type Counterparts , DOI=

    Witteveen, Catherine , year=. Synthesis, Characterization, and Magnetic Properties of Layered Transition Metal Dichalcogenides and Their Delafossite-Type Counterparts , DOI=

    work page

  66. [66]

    Wypych and K

    F. Wypych and K. Sollmann and R. Schöllhorn , abstract =. Metastable layered chalcogenides 1T-MoS2, 2M-WS2 and 1T-Mo12W12S2: Electrochemical study on their intercalation reactions , journal =. 1992 , issn =. doi:https://doi.org/10.1016/0025-5408(92)90142-M , url =

    work page doi:10.1016/0025-5408(92)90142-m 1992

  67. [67]

    New strategies to prepare crystalline chalcogenides

    Xiong, Wei-Wei and Zhang, Guodong and Zhang, Qichun. New strategies to prepare crystalline chalcogenides. Inorg. Chem. Front. 2014. doi:10.1039/C4QI00013G

    work page doi:10.1039/c4qi00013g 2014

  68. [68]

    and Rodriguez, Efrain E

    Zhou, Xiuquan and Wilfong, Brandon and Vivanco, Hector and Paglione, Johnpierre and Brown, Craig M. and Rodriguez, Efrain E. , title =. Journal of the American Chemical Society , volume =. 2016 , type =. doi:10.1021/jacs.6b10229 , url =

    work page doi:10.1021/jacs.6b10229 2016

  69. [69]

    , journal =

    Goodenough, John B. , journal =. Theory of the Role of Covalence in the Perovskite-Type Manganites [. 1955 , month =. doi:10.1103/PhysRev.100.564 , url =

    work page doi:10.1103/physrev.100.564 1955

  70. [70]

    Goodenough , abstract =

    John B. Goodenough , abstract =. An interpretation of the magnetic properties of the perovskite-type mixed crystals La1−xSrxCoO3−λ , journal =. 1958 , issn =. doi:https://doi.org/10.1016/0022-3697(58)90107-0 , url =

    work page doi:10.1016/0022-3697(58)90107-0 1958

  71. [71]

    Progress of Theoretical Physics , volume =

    Kanamori, Junjiro , title =. Progress of Theoretical Physics , volume =. 1957 , month =. doi:10.1143/PTP.17.177 , url =

    work page doi:10.1143/ptp.17.177 1957

  72. [72]

    Progress of Theoretical Physics , volume =

    Kanamori, Junjiro , title =. Progress of Theoretical Physics , volume =. 1957 , month =. doi:10.1143/PTP.17.197 , url =

    work page doi:10.1143/ptp.17.197 1957

  73. [73]

    Theory of Superexchange Interaction , author =

    Antiferromagnetism. Theory of Superexchange Interaction , author =. Phys. Rev. , volume =. 1950 , month =. doi:10.1103/PhysRev.79.350 , url =

    work page doi:10.1103/physrev.79.350 1950