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arxiv: 1207.3259 · v1 · pith:2I2VXHAGnew · submitted 2012-07-13 · ❄️ cond-mat.stat-mech

On extrapolation of virial coefficients of hard spheres

classification ❄️ cond-mat.stat-mech
keywords coefficientsvirialextrapolationhardmethodsspheresvaluesbeen
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Several methods of extrapolating the virial coefficients, including those proposed in this work, are discussed. The methods are demonstrated on predicting higher virial coefficients of one-component hard spheres. Estimated values of the eleventh to fifteenth virial coefficients are suggested. It has been speculated that the virial coefficients, B_n, beyond B_{14} may decrease with increasing n, and may reach negative values at large n. The extrapolation techniques may be utilized in other fields of science where the art of extrapolation plays a role.

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