pith. sign in

arxiv: 1612.03595 · v1 · pith:2OL3UALZnew · submitted 2016-12-12 · ❄️ cond-mat.soft

Multiblob coarse-graining for mixtures of long polymers and soft colloids

classification ❄️ cond-mat.soft
keywords descriptionfullsystemsdegreeseffectivefreedommixturesnanocomposites
0
0 comments X
read the original abstract

Soft nanocomposites represent both a theoretical and an experimental challenge due to the high number of the microscopic constituents that strongly influence the behaviour of the systems. An effective theoretical description of such systems invokes a reduction of the degrees of freedom to be analysed, hence requiring the introduction of an efficient, quantitative, coarse-grained description. We here report on a novel coarse graining approach based on a set of transferable potentials that quantitatively reproduces properties of mixtures of linear and star-shaped homopolymeric nanocomposites. By renormalizing groups of monomers into a single effective potential between a $f$-functional star polymer and an homopolymer of length $N_0$, and through a scaling argument, it will be shown how a substantial reduction of the to degrees of freedom allows for a full quantitative description of the system. Our methodology is tested upon full monomer simulations for systems of different molecular weight, proving its full predictive potential.

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.