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arxiv: 1702.07217 · v1 · pith:34MMTQMFnew · submitted 2017-02-23 · ❄️ cond-mat.soft

Ordering of hard rectangles in strong confinement

classification ❄️ cond-mat.soft
keywords densityorderingparallelfluidhardstructureswallclose
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Using transfer operator and fundamental measure theories, we examine the structural and thermodynamic properties of hard rectangles confined between two parallel hard walls. The side lengths of the rectangle ($L$ and $D$, $L>D$) and the pore width ($H$) are chosen such that maximum two layers are allowed to form in planar order ($L$ is parallel to the wall), while only one in homeotropic order ($D$ is parallel to the wall). We observe three different structures: (i) a low density fluid phase with parallel alignment to the wall, (ii) an intermediate and high density fluid phase with two layers and planar ordering and (iii) a dense single fluid layer with homeotropic ordering. The appearance of these phases and the change in the ordering direction with density is a consequence of the varying close packing structures with $L$ and $H$. Interestingly, even three different structures can be observed with increasing density if $L$ is close to $H$.

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