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arxiv: 1608.05625 · v1 · pith:3EWEN3EMnew · submitted 2016-08-19 · 🧮 math-ph · math.AP· math.MP

The maximal excess charge in M\"uller density-matrix-functional theory

classification 🧮 math-ph math.APmath.MP
keywords theorychargeelectronsnucleusulleratombindbound
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We consider an atom described by M\"uller theory, which is similar to Hartree-Fock theory, but with a modified exchange term. We prove that a nucleus of charge Z can bind at most Z+C electrons, where C is a universal constant. Our proof proceeds by comparison with Thomas-Fermi theory and a key ingredient is a novel bound on the number of electrons far from the nucleus.

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