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arxiv: 1810.11249 · v2 · pith:3HFNC6SWnew · submitted 2018-10-26 · ⚛️ physics.chem-ph · cond-mat.str-el

Strong-interaction limit of an adiabatic connection in Hartree-Fock theory

classification ⚛️ physics.chem-ph cond-mat.str-el
keywords adiabaticconnectionfunctionallimitstrong-interactiontheorydensityhartree-fock
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We show that the leading term in the strong-interaction limit of the adiabatic connection that has as weak-interaction expansion the Moeller-Plesset perturbation theory can be fully determined from a functional of the Hartree-Fock density. We analyze this functional and highlight similarities and differences with the strong-interaction limit of the density-fixed adiabatic connection case of Kohn-Sham density functional theory.

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