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arxiv: 1007.5042 · v1 · pith:3QWR36LPnew · submitted 2010-07-28 · ⚛️ physics.chem-ph

Classical photo-dissociation dynamics with Bohr quantization

classification ⚛️ physics.chem-ph
keywords classicalexpressionbohrphoto-dissociationquantizationavailableconsistentcross
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The standard classical expression of the state-resolved photo-dissociation cross section is not consistent with an efficient Bohr quantization of product internal motions. A new and strictly equivalent expression not suffering from this drawback is proposed. This expression opens the way to more realistic classical simulations of direct polyatomic photo-dissociations in the quantum regime where only a few states are available to the products.

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