On the Classical Description of Nuclear Motion
classification
⚛️ physics.chem-ph
keywords
classicaldescriptionalternativeapproachapproximationbasisborn-oppenheimermechanical
read the original abstract
Severe methodological and numerical problems of the traditional quantum mechanical approach to the description of molecular systems are outlined. To overcome these, a simple alternative to the Born-Oppenheimer approximation is presented on the basis of taking the nuclei as classical particles.
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